Components of a typical disposable
diaper
1)
Polyethylene or cloth-like film:
This is used as the back sheet that prevents the liquids from leaking out of
the diaper. The back-sheet can also be given a cloth-like look, by adding a
thin polypropylene non-woven sheet to the film, using either the hot melt
process or the heat and pressure method with direct extrusion to the nonwoven.
Contrary to popular belief, the cloth-like back sheet is not cloth -it is made
of plastics. Breathable cloth-like material can also be used instead of the
film. Not many know that even a breathable diaper with 200 ml of urine loses
less than 2.5% of its weight over a period of 24 hours and this evaporation is
enough the cool the diaper, which may not be as comfortable at night. For more
information about “breathability” please use this link: breathable diapers.
2)
Tissue: A special tissue paper that is
different from the regular bathroom tissue and has a higher elasticity and wet
strength is another important component of a diaper. The tissue essentially
serves as a carrier for the pad (the pad is the absorbent core of the diaper)
and helps reduce the pin holes created during the compression process carried
out by continuous drum forming systems. This tissue, typically at 16 grams/m2
(also abbreviated as GSM) or more, protects the inner plastic from the
superabsorbent particles. Instead of tissue, it is possible to use a low gage
SMS nonwoven material as the carrier (for the pad), it can be placed right next
to the back sheet or as a full wrap material around the core. In order for the
SMS carrier to be cost competitive against tissue paper, it needs to be less
than 12 GSM.
3)
Hot Melts: They are used to glue the different
components of the diaper, such as the pad and the elastics. They are made of a
mixture of resins, oils and tackifiers. The hot melt adhesive is applied in
molten form and when it cools down it provides the required bonding force to
glue the materials. Most of the times two types of adhesives are used: a
construction adhesive, for the back sheet and the nonwovens, and an elastomeric
adhesive, for the leg and waist foam elastics. The elastomeric adhesive has
higher elasticity and bonding strength and it is generally more expensive than
construction adhesives. When the diaper pad is very thin, another specialty
adhesive known as “pad integrity adhesive” is also used to add strength to the
diaper core when it is wet. This integrity adhesive is especially useful when
SAP loadings exceed 25% of the total pad weight -i.e. when the weight of the
SAP is more than a quarter of the weight of the pad. For a list of hot melt
suppliers follow this link: Hot Melts.
4)
Hydrophobic Non-woven: It is
used as a top sheet for the leg cuffs; it prevents water from passing through.
It is made of polypropylene resin without any added surface surfactants. The
hydrophobic nonwoven prevents leakage out of diaper. By applying a surfactant
to a restricted area, it is possible to make a roll of hydrophobic nonwoven
only partially phallic. This is known as the Zebra process and it is an
important feature designed to avoid leakage during leg cuff construction.
5)
Hydrophilic Non-woven: It is the
main top sheet, the top surface that is in contact with the baby’s skin. It
allows the liquids to flow into the diaper core. The difference between the two
non-woven’s (phallic and phobic) is the surfactant treatment used in the
process. The surfactant treatment reduces the surface tension of the nonwoven,
reduces the contact angle with the liquid and allows it to pass. Flow dynamics
within the diaper core prevent liquids from returning to the surface. Most
nonwovens used in diapers are made with the spun bonding process, though it is
possible to use thermal bonded nonwovens also, which are softer but have lower
resistance and strength. Trough Air Bonded nonwovens which are more lofty, can
also be used. For nonwoven suppliers use this link: Nonwovens.
6)
Elastics: Used to improve the fit of the
diaper, usually made of polyurethane or polyester foam, synthetic rubber or
Lycra® (also known with the generic name Spandex). They are used in cuffs, for
the waist and the legs; they can also be used as lateral side panels and in
tape construction. Most gasketing cuffs use spandex to provide a seal with the
baby’s legs. Spandex can stretch as much as 400% of its original length before
it breaks, however it is typically used at less than 300% stretch. New
generations of softer and stronger elastic materials are reportedly in the
pipeline. For a list of suppliers use this link: Elastomeric.
7)
Lateral Tapes: In premium diapers, Velcro type materials have been used to
provide mechanical grip, it is also known as the “hook tape”. In lower priced
diapers, adhesive tapes made of polypropylene are used. Then there are new
versions of elasticized Nonwoven Velcro Tapes. In a few years baby diapers may
replace training pants with the help of these new stretchable fastening systems
that offer the same characteristics to the consumer but cost less. Some adult
diapers use what is called the “target tape” system, where the tape has two
adhesive tabs to avoid the need for a frontal tape. This is a cheaper
alternative for adult diapers but not as good as the one using a frontal tape
which does not require repositioning of the tape on top of the target. For a
list of suppliers use this link: Tapes and Closure
systems.
Frontal Tapes: This is used to facilitate multiple repositioning of the
lateral tape without tearing the back-sheet, it is made of polypropylene film
and attached to the front of the diaper with adhesive. Its use has helped to
reduce the thickness of the poly film without the risk of potential tears
associated with the opening of the lateral tapes from the backsheet. In premium
diapers, a special loop system has been developed in order to use of Velcro
type fasteners (also called the “hook and loop” system). This loop tape can use
a “locked loop” or a “brushed loop” in order to provide a softer texture or a
stronger grip. A new generation of nonwoven materials expected to be
commercialized in a few years, may eliminate the need for frontal tapes – the
whole backsheet will be used to reposition mechanical tapes. The frontal tape
can have a printed design which can be random or synchronized, some patents may
protect the use of synchronized printing in some markets. Tapes and Clossure
systems.
9)
Cellulose: Used in the construction of the
pad, it gives integrity and absorbing capacity to the diaper. The capacity of
normal cellulose pulp is around 10 cc of water per gram of pulp when the diaper
is in “free swell” but less than 2 cc when subjected to 5 KPa of pressure; that
is why a superabsorbent material is also needed to hold the liquids under
pressure. Cellulose comes from pine trees, generally obtained from well managed
forests. Liquids are absorbed by the capillaries in the void spaces between the
fibers and the surface tension angle between the fibers and the water. Typical
fiber length used in diapers is about 2.6 mm. An alternative to pulp is to use
air laid synthetic fibers. However, it is still difficult for air laid
synthetics to compete with pulp, unless it is a niche market product and
thickness is more important for the consumer (as in case of some sanitary
napkins and the adult diapers used by active people) than the cost. Cellulose
acetate, the material used to make cigarette filters, has been used in some
absorbent products. PP synthetic fibers have also been attempted for absorbent
core formation. For a list of pulp suppliers use this link: Fluff Pulp.
10)
Acquisition and Distribution Layer:
Also known with its abbreviation ADL, it is a sub layer used between the top
sheet and the absorbent core. Sometimes used in full length but mostly
preferred as a patch near the target zone where urine is most likely to be
deposited. This sub layer is specially needed when the absorbent core is very
thin -the sub layer quickly moves liquids into the absorbent core and reduces
potential leakage. The ADL is very important to provide a sense of dryness to
the skin, providing additional separation between the wet pad and the skin.
ADL’s should be used whenever the mix of SAP in the absorbent core exceeds
about 15% by weight or when the liquid penetration time requires a boost in
order to avoid diaper leakage due to liquid accumulation inside the diaper.
ADL’s are made either of through air bond (TAB) nonwovens, “curly” fibers such
as in P&G’s pampers and some Ontex diapers, or some kind of “high loft”
nonwoven. An aperture film, made of perforated plastic film, has also been used
successfully in some markets. Lower priced diapers sometimes use resin bonded
nonwovens, but they do not work as well. For acquisition nonwoven suppliers use
this link: Nonwovens.
11)
Sodium Polyacrylate: Also known as super-absorbent or “SAP” (super absorbent polymer), Kimberly Clark used to call it
SAM (super absorbent material). It is typically used in fine granular form
(like table salt). It helps improve capacity for better retention in a
disposable diaper, allowing the product to be thinner with improved performance
and less usage of pine fluff pulp. The molecular structure of the polyacrylate
has sodium carboxylate groups hanging off the main chain. When it comes in
contact with water, the sodium detaches itself, leaving only carboxyl ions.
Being negatively charged, these ions repel one another so that the polymer
unwinds and absorbs water, which is attracted by the sodium atoms. The polymer
also has cross-links, which effectively leads to a three-dimensional structure.
It has high molecular weight of more than a million; thus, instead of getting
dissolved, it solidifies into a gel. The Hydrogen in the water (H-O-H) is
trapped by the acrylate due to the atomic bonds associated with the polarity
forces between the atoms. Electrolytes in the liquid, such as salt minerals
(urine contains 0.9% of minerals), reduce polarity, thereby affecting
superabsorbent properties, especially with regard to the superabsorbent
capacity for liquid retention. This is the main reason why diapers containing
SAP should never be tested with plain water. Linear molecular configurations
have less total capacity than non-linear molecules but, on the other hand,
retention of liquid in a linear molecule is higher than in a non-linear
molecule, due to improved polarity.
The
superabsorbent can be designed to absorb higher amounts of liquids (with less
retention) or very high retentions (but lower capacity). In addition, a surface
cross linker can be added to the superabsorbent particle to help it move
liquids while it is saturated. This helps avoid formation of “gel blocks”, the
phenomenon that describes the impossibility of moving liquids once a SAP
particle gets saturated. Please read the history section for more information.
To get more answers about this superabsorbent material, please use the link: Frequent questions
about SAP
12)
Top Sheet surface add-on lotions:
In
order to create novelties for product differentiation, several topical lotions
are added to the nonwoven top sheet, among others: Aloe Vera, Vitamin E,
Petrolatum, Almond Oil, Vitamin D, Oat Extract, Jojoba, etc. There is another
trend to use antibacterial lotions (such as tertiary ammonia or silver salt
compounds); however, many pediatricians are against its use for obvious
reasons.
13) Decorated Films and wetness
indicators: For even greater product
differentiation, some diapers use decorated films underneath the cloth-like
backsheet. Some use as many as nine inks with all kinds of well known
characters such as Disney, Sesame Street, Soccer teams, etc. Another gimmick
they use is a wetness indicator. This is typically used for adult products but
some baby diapers also use it.
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